Document Type : Original Research Paper
Authors
1 Faculty of Chemistry, Teacher Training University, Tehran, Iran
2 Faculty of Science, University of Kurdistan, , Iran
3 Department of Chemistry, Islamic Azad University, Shahr-e Rey Branch,Tehran,Iran
Abstract
The aim of this paper is to provide a link between research projects and education to optimize teaching and learning of related subjects. In a research project, three compounds including an intermolecular proton transfer compound, a hydrated carboxylic acid, and a metallic complex were synthesized, all of them have non-covalent interactions such as O−H∙∙∙O, O−H∙∙∙N and C−H∙∙∙O hydrogen bonds as well as van der Waals forces and π-π stacking resulting to different supramolecular structures. The structures of compounds are characterized by single crystal X-ray diffraction method. The classic concepts and definitions related to the subject are given in the last section.
Keywords
- Chelidamic acid
- Pyridine-2
- 6-dicarboxylic acid
- Zinc
- Hydrogen bond
- Stacking
- Proton transfer
- Supramolecular chemistry
- Crystal structure
Main Subjects
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Like the above structure, there are many other examples with such weak interactions like C−H···O, N−H···F–C and O−H···π (see Table 10). As a conclusion, the interactions discussed here and any other interactions such as van der Waals or ion pairing generally have an electrostatic force foundation.
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Figure 21 Inter- and intramolecular C−H···Cl and C−H···S as well as C−H···π contacts in a SbIII complex.
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